I believe you are referring to the Document Map (Word 97-2007) or the Navigation pane (Word 2010 and later).
To display the Document Map: Click View | Document Map.
To display the Navigation pane: Click View tab | Navigation Pane.
To see all headings, you may have to right-click and choose that option (as some heading levels may be hidden by default).
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Stefan Blom
Microsoft Word MVP
Microsoft 365 apps for business
Windows 11 Professional
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