As Andrew says, your requirement is vague. If you want to open a series of documents when you start Word then see Save Record And Close

If you want to load a set of add-in templates when Word starts then if you have not changed the preferred startup folder it can be located (in English language versions of Windows) by typing
%appdata%\Microsoft\Word\Startup
in the Windows File Explorer Address bar and pressing Enter.

You may find Load Word add-ins for the current session only useful.



Word (and Excel) are poor with regard to working document folders. They used to be better up to Word 2010, but then Microsoft became fixated on cloud based file storage as another potential revenue stream. To address this see also Select Document Template which makes accessing templates from various folders much more practical.

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Graham Mayor - MS MVP (Word) (2002-2019)
Visit my web site for more programming tips and ready made processes www.gmayor.com

In the Excel folder
C:\Users\username\AppData\Roaming\Microsoft\Excel\ XLStart you can create shortcuts to .xlsx spreadsheets and when you start Excel they open automatically.

Previously in Word there was a Work folder that worked the same way.

Basically, I'm looking for the equivalent of XLStart in Word 2010.