As long as the printer is correctly configured for duplex printing, you should be able to just print from within Word, via File | Print. Make sure your duplex-capable printer is selected in the Print window, and click the Print button. You shouldn't have to change any of the options related to duplexing in Word. In particular, you shouldn't select the option for manual duplexing in Word.
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Stefan Blom
Microsoft Word MVP
Microsoft 365 apps for business
Windows 11 Professional
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