The colour scheme dropdown does not appear to be exposed to VBA. Frankly if you need a specific colour in your template project, it would be better to setup the styles you require including colour in that template and ignore the schemes. The simple desktop application ColorCop is brilliant for matching colours.
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Graham Mayor - MS MVP (Word) (2002-2019)
Visit my web site for more programming tips and ready made processes www.gmayor.com
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