Okay, so after a few hours of messing about, I made some progress. I can get Excel to open now, but that first error constantly pops up -- there's a faulty Microsoft Exchange account added, and I can't work out how to remove it.
Attempting to remove the account from the E-mail tab of Account Settings gets me the error:
Quote:
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You cannot delete this Outlook data file. Configuration information in the file is being copied to your new default data file. You can delete the file after the information is copied.
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It persists even after 6+ hours of waiting, and multiple reboots. How can I unlock and remove this account?