If you have a language version of Office 2007 that includes Portuguese proofing tools, you should be able to enable those in Office Setup (start it from Control Panel | All Control Panel Items | Programs and Features).
If you do not have a language version of Office 2007 that includes Portuguese, what you need is a Portuguese language pack. Unfortunately, these are no longer sold by Microsoft, so you'll have to try getting it from third-party.
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Stefan Blom
Microsoft Word MVP
Microsoft 365 apps for business
Windows 11 Professional
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