Well, see if this helps... I have major (thesis-esque) documents that use fancier formatting for the ToC. See the picture for my design - in this case, I use 4 different levels of ToC: SECTION X; Chapter #; #.#; #.#.#.
Go to Home tab --> Styles --> Manage Styles --> Edit
and you can select ToC 1 through ToC 9 to edit separately. Then in my case for ToC 1, I selected it --> Modify then selected Bold, centred, don't show page #s, etc.
Hope this helps a little. Not sure how I would get the full-page underline without "cheating", but there may be something under Modify for that too...?
Bryan
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