I was working a different issue and found that I can reproduce your symptoms.
Send/Receive Define Groups (Ctrl-Alt-s).
{Select "All Accounts"} -> Edit
{Select an account}
(o) Use the custom behavior defined below
{In the Folder Options pane}
If a folder is not checked, then the Outlook initial sync and Sync All (F9) do not pull in new mail. But if I switch to that folder, or open it in a New Window, it does a sync on that folder.
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