For certain languages, additional options may be available. I am not sure which additional options would apply to Hebrew. I take it you have installed full support for Hebrew on your system? If you have, and you still don't see the alignment option you are asking for, the conclusion is that it isn't supported. You can send feedback to Microsoft, of course.
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Stefan Blom
Microsoft Word MVP
Microsoft 365 apps for business
Windows 11 Professional
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