The default "Save" location is usually C:\Users\Username\Documents but Office remembers the location where you saved your last document. Maybe you chose another 'save-to' location previously?
To make this into 'Desktop' again create a new document and choose 'Desktop' as the location to save-to. You can then delete the document after saving it. I think you'll find that this will cause later documents to get saved there as well.
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