It is not fully clear what you want to do. Is this what you are looking to do?
Code:
Sub HiSpell()
Dim aRng As Range, aWord As Range
Set aRng = ActiveDocument.Range
aRng.LanguageID = wdEnglishUS
aRng.NoProofing = False
For Each aWord In aRng.Words
If CheckSpelling(aWord.Text) = False Then
aWord.InsertBefore "##"
aWord.HighlightColorIndex = wdYellow
End If
Next aWord
End Sub