Are you trying to write a web page rather than a document?
Did you read the
first link?
The
Columns feature in Word is for newspaper-style, snaking, columns.
Tables are for parallel structures. You can have heading styles in tables.
You can also have non-heading styles that look like heading styles. They will look like headings but not show up in the Navigation Pane nor in a Table of Contents.
Why use Microsoft Word’s built-in heading styles? by Shauna Kelly