Hi Rowan,
Have you tried printing the page? What you're seeing may be no more than a display issue. You should also be able to set the colour in Word to 204.0.1, the same as your image. Do note too that Word know nothing of whatever tweaks you may have done in Photoshop regarding monitor/printer colour calibration.
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Cheers,
Paul Edstein
[Fmr MS MVP - Word]
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