Try this one
Code:
Sub testaddshape()
Dim myshape As Shape
Set myshape = ActiveDocument.Shapes.AddPicture(FileName:="c:\test\overlay.png", _
LinkToFile:=False, _
SaveWithDocument:=True, _
Left:=0, _
Top:=0, _
Width:=ActiveDocument.Sections(1).PageSetup.PageWidth, _
Height:=ActiveDocument.Sections(1).PageSetup.PageHeight)
With myshape
.ZOrder msoSendBehindText
.WrapFormat.Type = wdWrapBehind
.LockAnchor = True
.RelativeHorizontalPosition = wdRelativeHorizontalPositionPage
.RelativeVerticalPosition = wdRelativeVerticalPositionPage
.Left = 0
.Top = 0
End With
End Sub