You can have any number of PST files open, but only one can be the default. If memory serves, Outlook 2010 will create a new PST file for each e-mail account, unless you specifically tell it to use the default data store. If you are not collecting data in the PST file file that is not the default, close it until you need information from it.
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Graham Mayor - MS MVP (Word) (2002-2019)
Visit my web site for more programming tips and ready made processes www.gmayor.com
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